Hola skip, si te refieres a como configurar el archivo .ini de la lista para juegos de pc tal vez puedo ayudarte yo lo tengo escrito asi y funciona correctamente:

### pc.ini (mamewah v1.61) ###

emulator_title PC Games

### List Generation Settings ###
rom_path D:\master\emu\juegos
rom_extension lnk
dat_file
nms_file
catver_ini_file
list_generation_method rom_folder

### Execution Settings ###
emulator_executable PC
commandline_format "[rompath]\[name].[romext]"{nodosbox}{nosafelaunch}
alt_commandline_format_1 [name]
alt_commandline_format_2 [name]
game_specific_config_path

### Artwork Locations ###
artwork_1_image_path d:\master\emu\juegos\Snaps
artwork_2_image_path
artwork_3_image_path
artwork_4_image_path
artwork_5_image_path
artwork_6_image_path
artwork_7_image_path
artwork_8_image_path
artwork_9_image_path
artwork_10_image_path
movie_preview_path
movie_artwork_no 1

### Screen-Saver Settings ###
enable_music_in_screensaver 0
saver_type launch_scr
movie_path c:\mamewah\ssmovie
movie_fullscreen 1
quit_delay 30
wrapper_executable
wrapper_commandline_format [name]
scr_file c:\mamewah\ms_pacman.scr

### External Application Settings ###
ipc_file_or_path
app_1_executable
app_1_commandline_format
app_2_executable c:\cpvw\cpvw.exe
app_2_commandline_format -b=c:\cpvw\images\mamewah.jpg
app_3_executable
app_3_commandline_format
auto_launch_apps

### Additional Settings ###
music_path c:\mamewah\music
lcd_display_file_path
lcd_fe_text

### Settings used by MAMEWAH ###
current_list 0

ahhh y para salir del juego y volver al mamewah debes usar la opcion salir del juego o presionar Alt + F4
espero que te sirva